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MSDS Name
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Uni-Sil
Silicone Sealer
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Revision Date
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February 1, 2010
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Section 1: Chemical Product and Company Identification
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Product Name
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Uni-Sil
Silicone Sealer
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CAS Number
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none
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HMIS Hazard Rating
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Health: 2, Fire: 1,
Reactivity: 0
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Company
Identification
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McGill
AirSeal LLC
2400 Fairwood Avenue
Columbus, Ohio 43207
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Contact
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McGill
AirSeal LLC
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Telephone
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(800)624-5535,
(614)829-1200
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Fax
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(614)829-1488
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Chemtrec
(24-hour)
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(800)424-9300
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Chemtrec
International
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(703)527-3887
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Product Class
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silicone elastomer
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Product Use
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sealer
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Product Code
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008911
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Section 2: Composition and Information about Ingredients
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Hazardous Ingredients
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CAS Number
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Percent
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triacetoxyethylsilane
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17689-77-9
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≤2
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methylsilanetriyl
triacetate
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4253-34-3
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≤2
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distillates
(petroleum),
hydro-treated middle
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64742-46-7
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≤26
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naptha
(petroleum),
hydro-treated heavy
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64742-48-9
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≤26
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OSHA
PELs and ACGIH TLVs are listed in Section 8 where applicable.
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Section 3: Hazard Identification
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Acute Effects
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Inhalation
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Irritates respiratory passages
very slightly.
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Ingestion
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No significant effects expected from
a single, short-term exposure.
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Skin
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May cause moderate
irritation.
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Eye
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Direct contact may cause moderate
irritation.
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Prolonged/Repeated Exposure Effects
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Inhalation
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No known applicable information.
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Ingestion
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No known applicable information.
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Skin
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No known applicable information.
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Signs and Symptoms of Overexposure
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Inhalation
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No known applicable information.
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Ingestion
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No known applicable information.
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Skin
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No known applicable information.
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Medical Conditions Aggravated by Exposure
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Inhalation
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No known applicable information.
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Ingestion
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No known applicable information.
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Skin
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No known applicable information.
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Primary Route(s)
of Entry
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Ingestion, yes; inhalation,
yes; skin, yes; eye, yes
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Section 4: First Aid Measures
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Eye Contact
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Hold eyelids apart and flush
with plenty of water for at least 15 minutes. Seek medical attention.
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Skin Contact
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Remove from skin and wash with
soap and water. Contact a physician if irritation develops or persists.
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Inhalation
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Remove individual to fresh air.
No first aid should be needed. If difficulty persists, seek medical attention.
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Ingestion
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No first aid should be needed.
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Section 5: Fire-Fighting Measures
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Flash Point
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n/a
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Explosive Range
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Lower explosive limit: Not determined
Upper explosive limit: Not determined
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Autoignition Temperature
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Not determined
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Extinguishing Media
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On small fires use carbon dioxide,
dry chemical, or water spray. On large fires use dry chemical, foam, or water spray.
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Hazardous Combustion
Products
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Thermal breakdown of this
product during fire or very high heat conditions may evolve the following hazardous
decomposition products: carbon oxides and traces of incompletely burned carbon compounds,
formaldehyde, and silicone dioxide. When heated to temperatures about 150°C in the presence
of air, product can form formaldehyde vapors. Formaldehyde is a potential cancer hazard, a
known skin and respiratory sensitizer, and an irritant to the eyes, nose, throat, skin, and
digestive system.
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Fire-Fighting
Procedures
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Wear a NIOSH approved
self-contained breathing apparatus. Wear appropriate personal protective equipment. Water
can be used to keep fire-exposed containers cool. Determine the need to evacuate or isolate
the area according to your local emergency plan.
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Section 6: Accidental Release Measures
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Containment/Clean-up Techniques
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Isolate the hazard area.
Keep unnecessary and unprotected personnel from entering the area. Wear all appropriate
personal protection equipment (PPE) (See Section 8). Wipe up or scrape up and contain
for salvage or disposal. Clean the area as appropriate, because the spilled materials
may present a slip hazard. Final cleaning may require use of steam, solvents, or detergents.
Dispose of the saturated absorbent or cleaning materials appropriately, because spontaneous
heating may occur. Federal, state, and local laws and regulations may apply to releases
and disposal of the material, as well as the materials used to cleanup the releases.
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Section 7: Handling and Storage
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Handling
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Use with adequate ventilation.
Product evolves acetic acid when exposed to water or humid air. Provide ventilation during
use to control acetic acid within exposure guidelines or use respiratory protection. Avoid
eye contact. Avoid skin contact.
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Storage
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Use reasonable care and store
away from oxidizing materials. Keep container closed and store away from water or moisture.
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Section 8: Exposure Controls and Personal Protection
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Occupational Exposure Limits
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triacetoxyethylsilane
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ACGIH
TLV-TWA
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10
ppm
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ACGIH
TLV-STEL
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15
ppm
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OSHA
PEL-TWA
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10
ppm
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Engineering Controls
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Use local exhaust as needed
to maintain occupational exposure limits. Maintain standard plant ventilation.
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Respiratory
Protection
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Where exposure limits may be
exceeded, select a NIOSH approved respirator with appropriate Protection Factor and cartridge
for the specific contaminants. Follow requirements for respiratory protection in OSHA 1910.134.
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Skin
Protection
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Where skin contact can occur,
wear impervious gloves. Wash at mealtime and end of shift. Contaminated clothing and shoes should
be removed as soon as practical and thoroughly cleaned before reuse.
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Eye
Protection
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Chemical splash goggles
(ANSI Z87.1 or approved equivalent).
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Other
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Facilities storing or utilizing any
chemical should be equipped with an eyewash facility and a safety shower.
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Section 9: Physical and Chemical Properties
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Form
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paste
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Appearance/Color
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aluminum/white/clear/black/limestone/bronze
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Odor
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acetic acid odor
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Solubility (in water)
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not determined
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pH Value
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not determined
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Boiling Range/Point
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not determined
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Evaporation Rate
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not determined
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Specific Gravity
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0.96 (at 25°C)
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Volatile Content
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not determined
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Viscosity
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not determined
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Section 10: Stability and Reactivity
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Stability
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This product is stable.
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Hazardous
Polymerization
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Hazardous polymerization will
not occur.
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Conditions
to Avoid
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none
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Hazardous Decomposition
Products
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Oxidizing material can cause a
reaction. Water, moisture, or humid air can cause hazardous vapors to form as described
in Section 8.
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Section 11: Toxicological Information
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No known applicable information
on special hazards on components.
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Section 12: Ecological Information
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This formulation has not been
tested for environmental effects.
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Section 13: Disposal Considerations
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RCRA Hazard Class
(40 CFR 261)
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When a decision is made to
discard this material, as received, is it classified as a hazardous waste? No.
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Container Disposal
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Disposal of this container
should comply with all applicable federal, state, and local regulations.
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Section 14: Transport Information
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DOT
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Not
subjected to DOT.
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Ocean Shipment
(IMDG)
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Not subjected
to IMDG code.
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Air Shipment
(IATA)
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Not subjected to
IATA regulations.
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Section 15: Regulatory Information
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SARA Title III Chemical Listings
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Section 302 Extremely Hazardous Substances
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none
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Section 304 CERLA
Hazardous Substances
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none
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Section 312 Hazard Class
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Acute, Yes;
Chronic, No; Fire, No; Pressure, No; Reactive, No
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Section Title 313
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None present or none
present in regulated quantities.
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Toxic Substances Control Act (TSCA)
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All components of this
product are listed on the TSCA inventory except as exempted.
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California Proposition 65 (Teratogen)
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WARNING: The chemical(s) noted below
and contained in this product, are known to the state of California to cause cancer, birth
defects, or other reproductive harm. None known.
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Chemical
Name
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CAS Number
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Wt/Wt % is Less Than
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dimethyl
siloxane,
hydroxyl-terminated
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70131-67-8
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87.0
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silica,
amorphous
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7631-86-9
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10.0
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Chemical Name
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CAS Number
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Wt/Wt % is Less Than
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silica,
amorphous
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7631-86-9
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10.0
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Chemical Name
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CAS Number
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Wt/Wt % is Less Than
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dimethyl
siloxane,
hydroxyl-terminated
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70131-67-8
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87.0
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silica,
amorphous
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7631-86-9
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10.0
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distillates
(petroleum),
hydro-treated middle
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64742-46-7
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25.0
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triacetoxyethylsilane
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17689-77-9
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2.0
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Section 16: Other Information
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Disclaimer
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While the information and
recommendations set forth herein are believed to be accurate as of the data hereof, McGill
AirSeal LLC makes no warranty, express or implied, with respect thereto and disclaims all
liability from reliance thereon.
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©
Copyright 2001-2011 McGill AirSeal LLC
e-mail us: sales@mcgillairseal.com
An
enterprise of United McGill Corporation—Family owned and operated since 1951
All the trademarks (™) and registered trademarks (®) in this
Web site are the property of United McGill Corporation.
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